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教育经历:
1998 - 2003,中国科学院大连化学物理研究所,物理化学,硕博连读,博士
1994 - 1998,山东大学,应用化学,学士
工作经历:
2018 - 至今,东南大学,化学化工学院,教授
2006 - 2018,东南大学,化学化工学院,副教授
2003 - 2004,日本山梨大学
1. 江苏省自然科学基金面上项目,BK20151408,有机溶剂升华干燥对氧化物气凝胶成型及微观结构的影响机理研究,2015/07-2018/06,10万元,已结题,主持。
2. 企业合作项目,8507040216,新材料公共技术服务平台建设协议,2017/10-2018/12,50万元,已结题,主持。
3. 东南大学高校基本科研业务费高水平论文项目,3207046418,具有特定三维网络结构的氧化物气凝胶的可控合成,2016/03-2017/12,8万元,已结题,主持。
4. 东南大学高校基本科研业务费专项资金,3207045411,无机氧化物气凝胶的干燥成型机制研究,2015/07-2016/06,5万元,已结题,主持。
5. 国家自然科学基金青年项目,21206018,过渡金属磷化物催化剂上微波辅助三氯乙烯加氢脱氯的研究,2013/01-2015/12,25万元,已结题,主持。
6. 国家自然科学基金面上项目,22275035,固态碳量子点的氢键组装与性能研究,2023/01-2026/12,54万元,在研,主持。
代表性论文:
[1] Xinyu Wang, Xu Yu, Pinyi He, Guohui Yang, Fu Qin, Yongkang Yao, Jiangliang Bai, Guojun Yuan, Lili Ren*. In Situ Phase Transformation Induced High Activity Nickel Molybdenum Catalyst for Enhancing High Current Density Water/Seawater Splitting, ACS Sustainable Chemistry & Engineering, 13: 3645, 2025.
[2] Pinyi He, Jianliang Bai, Fu Qin, Xinyu Wang, Xu Yu, Yongkang Yao, Lili Ren*. Regulation of the unconventional luminescence behaviors of phenylenediamine-based carbon dots with high PLQY values, Chemical Engineering Journal, 506: 160342, 2025.
[3] Xinyu Wang, Xu Yu, Pinyi He, Guohui Yang, Fu Qin, Yongkang Yao, Lili Ren*. Built-in electric field construction and lattice oxygen activation for boosting alkaline electrochemical water/seawater oxidation, Chemical Engineering Journal, 496: 154279, 2024.
[4] Fu Qin, Jianliang Bai, Pinyi He, Xinyu Wang, Shuang Wu, Xu Yu, Yongkang Yao, Lili Ren*. Light on multicolor fluorescent carbon dots from a single biomass precursor through simply tuning the solvothermal temperature and time strategy, Materials Today Chemistry, 34: 101816, 2023.
[5] Fu Qin, Jianliang Bai, Yaqing Zhu, Pinyi He, Xinyu Wang, Shuang Wu, Xu Yu, Lili Ren*. Searching for the true origin of the red fluorescence of leaf-derived carbon dots, Physical Chemistry Chemical Physics, 25: 2762, 2023.
[6] Jianliang Bai, Xinyu Wang, Yaqing Zhu, Guojun Yuan, Shang Wu, Fu Qin, Xu Yu, Lili Ren*. Polymer types regulation strategy toward the synthesis of carbonized polymer dots with excitation-wavelength dependent or independent fluorescence, Chinese Chemical Letters, 34: 107509, 2023.
[7] Xinyu Wang, Xu Yu, Shuang Wu, Pinyi He, Fu Qin, Yongkang Yao, Jianliang Bai, Guojun Yuan, Lili Ren*, Crystalline−amorphous interface coupling of Ni3S2/NiPx/NF with enhanced activity and stability for electrocatalytic oxygen, ACS Applied Materials & Interfaces, 15: 15533, 2023.
[8] JianliangBai, Guojun Yuan, Xu Chen, Lu Zhang, Yaqing Zhu, Xinyu Wang, Lili Ren*.Simple strategy for scalable preparation carbon dots: RTP, time-dependence fluorescenceand NIR behaviors, Advanced Science, 9: 2104278, 2022.
[9] YaqingZhu, Jianliang Bai, Zhujun Huang, Guojun Yuan, Lu Zhang, Xinyu Wang, LiliRen*. A universal strategy for preparing carbon quantum dot-basedcomposites with blue and green afterglow luminescence, MaterialsChemistry Frontiers, 5: 8161, 2021.
[10] GuojunYuan; Jianliang Bai; Lu Zhang; Xu Chen; Lili Ren*. The effect of Pvacancies on the activity of cobalt phosphide nanorods as oxygen evolutionelectrocatalyst in alkali, Applied Catalysis B: Environmental,284: 119693, 2021.
[11] JianliangBai, Guojun Yuan, Yaqing Zhu, Zhujun Huang, Lu Zhang, Xinyu Wang, Shuang Wu,Lili Ren*. Study on the Origin of Fluorescence by Using Dual-EmissionCarbon Dots, Journal of Physical Chemistry C, 125: 18543, 2021.
[12] LuZhang, Guojun Yuan, Xinyu Wang, Jianliang Bai, Yaqing Zhu, Lili Ren*, Non-negligibleoxygen atoms in transition metal phosphides: research on the role of oxygen in hydrodechlorination,Journal of Physical Chemistry C, 125(29): 15967, 2021.
[13] YushaMa, Xiaomeng Zhang, Jianliang Bai, Kai Huang*, Lili Ren*. Facile,controllable tune of blue shift or red shift of the fluorescence emission ofsolid-state carbon dots, Chemical Engineering Journal, 374: 787,2019.
[14] JianliangBai, Yusha Ma, Guojun Yuan, Xu Chen, Jing Mei, Lu Zhang, Lili Ren*. Solvent-controlledand solvent-dependent strategies for the synthesis of multicolor carbon dotsfor pH sensing and cell imaging, Journal of Materials Chemistry C,7: 9709, 2019.
[15] JingMei, Guojun Yuan, Yusha Ma, Xu Chen, Lili Ren*. Fe-doped alumina aerogels as a green heterogeneouscatalyst for efficient degradation of organic pollutants, CatalysisLetters, 149:1874, 2019.
[16] BingyingGao, Yusha Ma, Jing Mei, Shaoxiang Lu, Lili Ren*. Functional nanocomposite wet gels and aerogels induced by transition/lanthanidemetal ions coordination, Chemical Engineering Journal, 331:597-605, 2018.
[17] Shaoxiang Lu, Hanghui Xu, Bingying Gao, LiliRen*. A simple method to freely adjust the crystallinephase and micro-morphology of NixPy compounds, New Journal of Chemistry,41: 8497-8502, 2017.
[18] XiaomengLiu, Lili Ren*.The Influence of Polyethylene Glycol on the Synthesis and Activity of MoPfor the Hydrodechlorination of Trichloroethylene, RSC Advances, 6(9):7413-7418, 2016.
[19] QinghuiGuo, Lili Ren*.Hydrodechlorination of Trichloroethylene over MoP/γ-Al2O3Catalyst with High Surface Area, Catalysis Today, 264: 158-162, 2016.
[20] FengchaoCao, Lili Ren*, Xueai Li. Synthesisof high strength monolithic alumina aerogels at ambient pressure, RSC Advances, 5(23): 18025-18028, 2015.
[21] LiliRen*, Sumin Cui, Fengcao Chao, QinghuiGuo. An easy way to prepare monolithic inorganic oxide aerogels, AngewandteChemie International Edition, 2014, 53 (38), 10147-10149.
[22] LiliRen*, Tao Zhang. Reduction of NO with methane over Fe/ZSM-5 catalysts, Chinese Chemical Letters, 21: 674–677, 2010.
一、功能材料的研究。
1.多孔材料的制备。
包括多孔功能材料和催化剂载体的构筑,部分多孔材料工作介绍:课题组采用独特的有机溶剂升华干燥方法成功制备了一系列无机氧化物气凝胶。
图1 有机溶剂升华干燥制备气凝胶原理示意图
以下为本课题组制备的部分气凝胶样品图。
图2 系列无机氧化物气凝胶样品
图3 碳气凝胶样品
2. 碳量子点的制备与性能研究。
主要包括高性能碳量子点的构筑和发光性能调控。部分碳点工作介绍:课题组采用不同策略构筑了碳点与MOF的复合发光材料。
图4 碳点与MOF的组装策略
本课题组还通过加入三聚氰酸和碳点构筑氢键获得固态碳点,该碳点展示出了可调色的室温磷光现象,有望在指纹识别和高级信息加密等领域应用。
图5 通过氢键构筑的固态发光碳点
同时,我们还采用无溶剂法构筑了拥有一系列优异性能的固态碳点。
图6 无溶剂法构筑固态发光碳点
二、 多相催化的研究。
1. 催化剂的制备研究。特别是过渡金属磷化物催化剂的设计和性能研究,包括其活性晶面,晶面暴露程度、晶型结构、缺陷位等的研究;
2. 催化反应的研究。主要包括加氢脱氯反应的研究、电解水的研究。
部分催化相关工作介绍,课题组制备了具有磷空位的磷化钴催化剂并探究了其对电催化析氧反应性能的影响。
图7 磷化钴表面磷空位对OER性能的影响
通过尿素成功调控了磷化镍的晶型结构。
图8 尿素对磷化镍晶型结构的调控
通过氯离子成功调控了磷化镍的暴露晶面从而改善了其加氢脱氯催化活性。
图9 氯离子对磷化镍暴露晶面的调控
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